That had Muguruza serving for the set, and she took it, winning with yet another Williams unforced error, this one on her backhand.
Williams, 37, who was to become the oldest female Grand Slam winner if she prevailed, quickly fell apart after losing the first set, finishing the championship with a 7-5, 6-0 defeat. She got it without issue, getting the win. On the bright side, she will return to the top 10 for the first time since last fall. This would have been her 6th crown otherwise.
For the tournament, Murguruza only dropped 44 games, the least in the event.
"That's the kind of position I want to keep putting myself in".
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"Muguruza was in the zone", she said. You say, Oh, maybe I win.
They will be joined in the Royal Box by several former professional tennis players including Virginia Wade - the last British woman to lift the trophy in 1977 - and American and former world number one Billie Jean King.
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Williams won a pair of back-to-back Wimbledons.
Williams congratulated Muguruza in the post-match interview, telling her: "I know how hard you work, and I'm sure this means so much to you and your family". "She played really well".
Following the match, Muguruza reflected on the moment where she defeated someone she grew up watching.
That three-game sequence seemed to break the resolve of the American who then lost the second set to love in an equally astonishing turnaround.
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Martinez told Sportsweek: "She has the potential and she can win more". So there's definitely something for me to learn from this. That missed opportunity seemed to affect Venus more than it should have done for a player of such experience, because in the very next game, it was Muguruza who found the first break of the match.